... cos you gotta drink the juice, not take a tablet.
But, pumps are not something that comes from a supplement. It comes from blood rushing into the muscle cos you actually got off your butt and did something.
So, if you are chasing pumps, ditch the supps and have a decent meal 2 hours prior. Then cut your rest times to 15-30 seconds. Yes, you probably have to kick your ego in the balls and drop weight, but you will have a crazy pump.
Assuming that you are a typical gym rat and the pump is what you are looking for when doing biceps, try this:
Take about 10-15% off the weight you would normally use.
10 reps
30 sec rest
Repeat until you can't do another single good form rep. That may mean 20 sets. Do NOT cheat on the rest break. Be super strict. Use the stopwatch on your phone. Take 5 seconds off the rest period each week.
Bask in the glory of the pump.
After a couple of years, realise that it's just a pump and your arms still suck so start doing deadlifts. squats and overhead press.